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ToF Mass Spectroscopy

2017 Paper One

Question Four
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AQA A-level CHEMISTRY Paper 1 Inorganic and Physical ChemistryTuesday 13 June 2017


An 8-mark, 4-part question
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The relative atomic mass of titanium is 47.8 to one decimal place.
 
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Use the m/z value in the table = 46

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Mass of one atom of Ti-49:

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Don't forget to convert to kilograms.
 
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The kinetic energy is a constant as is the length of the tube

Here's one way (a little rearranging is required)...

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the length of the tube is the same for both ions, so...
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The kinetic energy is a constant as is the length of the tube for both ions. L, of course, is also a constant - we can cancel them out.
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The time of flight for the ion is:
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Note: there are other ways to solve this.

This question proved a step too far for a lot of students with many gaining no marks. The manipulation is fairly straightforward - I would brush up on maths skills if you found this difficult
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